I enjoy very much following the TED talks. Here is a list of my favorite talks that were posted until 2008.
I split the talks in four categories, each consisting of 5 entries. The brilliant ones are just brilliant, both content and delivery wise. The insightful ones are those that make a point I consider worth knowing. The entertaining ones are exactly that: fun to watch and listen. The hands-on category features nice examples of how to give demos. I added Hans Rosling both in the brilliant and in the hands-on section because I just like what he is doing and how he presents it :).
Brilliant:
Insightful:
Entertaining:
Hands-on: